79761-41-4Relevant academic research and scientific papers
Preparation of allenoyltrimethylsilanes
Cunico,Zhang
, p. 503 - 506 (1995)
Dehydrochlorination of 3-chloro-2- or -3-alkenoyltrimethylsilanes with DBU affords the parent 2,3-butadienoyltrimethylsilane, as well as 4-monoalkyl-and 4,4-dialkyl homologues.
SYNTHESIS OF Α-ALLENIC ALDEHYDES AND ALLENYL TRIMETHYLSILYL KETONES VIA (TRIMETHYLSILYLOXY)BUTATRIENES
Visser, R. G.,Brandsma, L.,Bos, H. J. T.
, p. 2827 - 2828 (2007/10/02)
α-Lithiated (trimethylsilyoxy)butatrienes, generated by 1,4-elimination of methanol from 1-trimethylsilyloxy-4-methoxy-2-alkynes with tert-butyllithium, give mixtures of α-allenic aldehydes and allenyl trimethylsilyl ketones which can be separated by dist
