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The chemical compound "(Rh(CO)((C6H5)3P)(C3HN2(CH3)2))2" is a rhodium-based complex with a unique structure. It consists of two identical units, each containing a rhodium atom at the center. The rhodium is coordinated with a carbon monoxide (CO) ligand, a triphenylphosphine ((C6H5)3P) ligand, and a 5-dimethyl-1H-pyrazole (C3HN2(CH3)2) ligand. The triphenylphosphine ligand is a bulky, electron-rich phosphorus-containing group that can influence the reactivity and stability of the complex. The 5-dimethyl-1H-pyrazole ligand is a bidentate nitrogen donor, which can form strong bonds with the rhodium center. The overall structure of the compound suggests that it may have potential applications in homogeneous catalysis, where such complexes are often used to facilitate chemical reactions under mild conditions. The specific arrangement of ligands around the rhodium atom can affect the electronic properties and reactivity of the complex, making it a subject of interest for chemists studying metal-ligand interactions and catalytic processes.

79772-08-0

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79772-08-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 79772-08-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,9,7,7 and 2 respectively; the second part has 2 digits, 0 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 79772-08:
(7*7)+(6*9)+(5*7)+(4*7)+(3*2)+(2*0)+(1*8)=180
180 % 10 = 0
So 79772-08-0 is a valid CAS Registry Number.

79772-08-0Downstream Products

79772-08-0Relevant academic research and scientific papers

Synthesis and characterization of Rh(CO)PPh3 and the X-ray structure of its toluene solvate

Louie, Brenda M.,Rettig, Steven J.,Storr, Alan,Trotter, James

, p. 503 - 508 (2007/10/02)

Details of the synthesis and physical properties of Rh(CO)PPh3 are given.Crystals of (triphenylphosphine)carbonylrhodium(I) - toluene (1:1) are triclinic, a = 10.690(2), b = 12.928(2), c = 13.998(2) Angstroem, α = 77.44(1), β = 83.50(1), γ = 72.70(1) deg, Z = 2, space group P1*.The structure was solved by conventional heavy-atom methods and was refined by full-matrix least-squares procedures to R = 0.039 and Rw = 0.048 for 5987 reflections with I ae 3?(I).The Rh(I) is in a distorted squareplanar environment with to Rh-N = 2.090(3) and 2.097(2), Rh-CO = 1.815(4), and Rh-P = 2.2700(8) Angstroem.The central six-membered RhGaN4 ring has a steep boat conformation with a Rh...Ga separation of 3.3819(4) Angstroem.

CARBOBNYLRHODIUM(I) DERIVATIVES OF 3,5-DIMETHYL- AND 3,5-BIS(TRIFLUOROMETHYL)PYRAZOLE

Banditelli, Guido,Bandini, Anna Laura,Bonati, Flavio,Minghetti, Giovanni

, p. 229 - 239 (2007/10/02)

Binuclear pyrazolato-bridged complexes such as 2, I or II, were obtained in alkaline solution from (OC)4Rh2Cl2 and 3,5-dimethylpyrazole (pz'H) or 3,5-bis(trifluoromethyl)pyrazole (pz''H), while in the absence of alkali (OC)2RhC

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