797757-25-6Relevant academic research and scientific papers
Unusual reactivity at a platinum center determined by the ligands and the solvent environment
Tamasi, Gabriella,Cini, Renzo,Intini, Francesco P.,Sivo, Maria F.,Natile, Giovanni
, p. 5081 - 5084 (2004)
The use of ancillary ligands resulted in the formation of (trans-[PtCl 3(OH2){N=C(OCH3)CH2CH 2CH2}2]+ (see structure), the first intermediate aqua species in the oxidation of platinum(II) to platinum(IV) to be isolated and characterized. In chloroform this complex, but not the corresponding chloro species, reacts with excess Cl- with O-demethylation of the ligands, indicating the importance of the coordinated water molecule.
