797757-83-6Relevant academic research and scientific papers
Heavy-metal-containing polyhedral metallasiloxane derived from an aminosilanetriol: Synthesis and structural characterization of [(PbO) 6(R2Si2O3)2] (R = (2,6.iPr2C6H3)N(SiMe3))
Nehete, Umesh N.,Chandrasekhar, Vadapalli,Jancik, Vojtech,Roesky, Herbert W.,Herbst-Irmer, Regine
, p. 5372 - 5374 (2004)
The reaction of RSi(OH)3 with Pb[N(SiMe3) 2]2 in a 1:1.5 molar ratio in THF/hexane afforded a hexameric lead(II)siloxane [(PbO)6(R2Si2O 3)2][R = (2,6-iPr2C6H 3)N(SiMe3)] 1. The molecular structure of 1 shows a central (PbO)6 motif enclosed by two outer R2-Si 2O3 siloxane ligands.
