797762-55-1Relevant academic research and scientific papers
Alkyne hydrosilylation catalyzed by a cationic ruthenium complex: Efficient and general trans addition
Trost, Barry M.,Ball, Zachary T.
, p. 17644 - 17655 (2007/10/03)
The complex [Cp*Ru(MeCN)3]PF6 is shown to catalyze the hydrosilylation of a wide range of alkynes, Terminal alkynes afford access to α-vinylsilane products with good regioselectivity. Deuterium labeling studies indicate a clean trans
Synthetic stitching with silicon: Geminal alkylation-hydroxylation of alkynyl carbonyl compounds
Trost, Barry M.,Ball, Zachary T.
, p. 13942 - 13944 (2007/10/03)
A new strategy for the synthesis of β-carbonyl-substituted tertiary alcohols from α,β-alkynyl ketones and esters has been demonstrated. A silicon tether is used to internally deliver an alkyl group, which, combined with a C-Si to C-O transformation, can r
