797784-80-6Relevant academic research and scientific papers
Hydroboration of methyl 2-acetamidoacrylate. II - New aspects of the reactivity of the resulting oxytriorganoborates
Denniel,Denniel, Valerie,Bauchat,Bauchat, Patrick,Carboni,Carboni, Bertrand,Danion,Danion, Daniel,Danion-Bougot,Danion-Bougot, Renee
, p. 6875 - 6878 (1995)
The heterocyclic borate complex obtained by hydroboration of methyl 2-acetamidoacrylate acts as an ambident nucleophile, affording N- or C-alkyl or acylalaninates according to experimental conditions. Mechanistic hypotheses are proposed to rationalize these results.
