79780-61-3

Usage

Appearance

White solid

Uses

Production of dyes and pigments
Manufacturing of pharmaceuticals
Manufacturing of agricultural chemicals

Applications

Building block for the synthesis of complex molecules
Versatile compound in various industries

Toxicity

Can be toxic if ingested or inhaled

Skin and eye irritation

May cause skin and eye irritation upon contact

Handling

Should be handled with care and proper safety measures

State

Solid

Color

White

Functional groups

Contains benzene ring, carbonitrile (CN), and amino (NH2) groups

Reactivity

Can undergo various chemical reactions due to the presence of functional groups

Potential hazards

May pose environmental risks if not handled or disposed of properly

Disposal

Requires proper disposal methods to minimize environmental impact

Chemical classification

Hazardous substance

Safety data sheet

A safety data sheet (SDS) should be available for proper handling, storage, and disposal instructions

Upstream product

• 20138-79-8 benzo[c][1,2,5]thiadiazole-4,7-dicarbonitrile 
• 15155-41-6 4,7-dibromobenzo[c][1,2,5]thiadiazole 
• 273-13-2 benzo[1,2,5]thiadiazole 
• 95-54-5 1,2-diamino-benzene 

Relevant academic research and scientific papers

Multi PCET in symmetrically substituted benzimidazoles

Proton-coupled electron transfer (PCET) reactions depend on the hydrogen-bond connectivity between sites of proton donors and acceptors. The 2-(2′-hydroxyphenyl) benzimidazole (BIP) based systems, which mimic the natural TyrZ-His190 pair of Photosystem II

Photodriven Multi-electron Storage in Disubstituted RuII Dppz Analogues

Four derivatives of the laminate acceptor ligand dipyrido-[3,2-a:2′,3′-c]phenazine (dppz) and their corresponding ruthenium complexes, [Ru(phen)2(dppzX2)]2+, were prepared and characterized by NMR spectroscopy, ESI-MS, and elemental analysis. The new ligands, generically denoted dppzX2, were symmetrically disubstituted on the distal benzene ring to give 10,13-dibromodppz (dppz-p-Br), 11,12-dibromodppz (dppz-o-Br), 10,13-dicyanodppz (dppz-p-CN), 11,12-dicyanodppz (dppz-o-CN). Solvated ground state MO calculations of the ruthenium complexes reveal that these electron-withdrawing substituents not only lower the LUMO of the dppz ligand (dppz(CN)22dppz), but that the para disubstitution results in a lower LUMO than the ortho disubstitution (dppz-p-CN(dppz-o-CN), and dppz-p-Brdppz-o-Br). The validity of the calculations was confirmed experimentally using cyclic voltammetry. Of the complexes evaluated in this study, only the dicyanodppz complexes showed multiple dppz-based reductions prior to reduction of the phen ligands. The capacity to form singly and doubly reduced dppz-based anions at modest reduction potentials was confirmed using a combination of spectroelectrochemical and chemical titration methods. When subjected to photolysis with visible light in the presence of a sacrificial donor, such as triethylamine, both cyano complexes showed multi-electron reduction. The other complexes only show a single reduction.

Solution-processable n-type semiconductors based on unsymmetrical naphthalene imides: Synthesis, characterization, and applications in field-effect transistors

A series of unsymmetrical naphthalene imide derivatives (1-5) with high electron affinity was synthesized and used in n-channel organic field-effect transistors (OFETs). They have very good solubility in common organic solvents and good thermal stability up to 320 °C. Their photophysical, electrochemical, and thermal properties were investigated in detail. They showed low-lying LUMO energy levels from -3.90 to -4.15 eV owing to a strong electron-withdrawing character. Solution-processed thin-film OFETs based on 1-4 were measured in both N2 and air. They all showed n-type FET behavior. The liquid-crystalline compounds 1 a, 1 b, and 3 showed good performance owing to the self-healing properties of the film in the liquid-crystal phase. Compound 3 has an electron mobility of up to 0.016 cm 2 V-1 s-1 and current on/off ratios of 10 4-105.Copyright