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APPROCHE CINETIQUE DU MECHANISME D'ISOMERISATION DE SPIROPHOSPHORANES OPTIQUEMENT ACTIFS
Klaebe, A.,Brazier, J. F.,Cachapuz Carrelhas, A.,Garrigues, B.,Marre, M. R.,Contreas, R.
, p. 2111 - 2122 (2007/10/02)
The polarimetric kinetic study, of the epimerisation of optically pure spirophosphoranes derived from α-aminoalcohols or α-aminoacids, leads to mechanistic conclusions.Evidence from isotopic, solvent and concentration effects and values of the activation
