79802-00-9Relevant academic research and scientific papers
Samarium-based Grignard-type addition of organohalides to carbonyl compounds under catalysis of CuI
Liu, Chen,Liu, Yongjun,Qi, Yan,Song, Bin,Wang, Liang,Xiao, Shuhuan
supporting information, p. 6169 - 6172 (2021/06/30)
Grignard-type additions were readily achieved under the mediation of CuI (10 mol%) and samarium (2 equiv.) by employing various organohalides,e.g.benzyl, aryl, heterocyclic and aliphatic halides (Cl, Br or I), and diverse carbonyl compounds (e.g.carbonic esters, carboxylic esters, acid anhydrides, acyl chlorides, ketones, aldehydes, propylene epoxides and formamides) to afford alcohols, ketones and aldehydes, respectively, with high efficiency and chemoselectivity, in which the organosamarium intermediate might be involved.
Iron-catalyzed allylation of ketones
Durandetti, Muriel,Périchon, Jacques
, p. 6255 - 6258 (2007/10/03)
Allylation of ketones has been efficiently performed using iron-complex catalysis and led to homoallylic alcohols in high yields.
STRUCTURE DU REACTIF D'IVANOV ET DE QUELQUES ORGANOMETALLIQUES ISSUS DES DERIVES PHENYLACETIQUES-II. STEREOCHEMIE DE LA CONDENSATION AVEC LA t-BUTYL-4 CYCLOHEXANONE
Mladenova, M.,Blagoev, B.,Gaudemar, M.,Gaudemar-Bardone, F.,Lallemand, J. Y.
, p. 2157 - 2164 (2007/10/02)
Ivanov reagent and some other analogous reagents (phenyl acetique serie) have been condensed with t-Bu-4 cyclohexanone in order to complete investigation of the reactive species.In all the cases, equatorial attack is highly predominant; it let suppose tha
