79802-21-4Relevant academic research and scientific papers
Palladium-Catalyzed Regioselective Coupling of Propargylic Substrates with Terminal Alkynes. Application to the Synthesis of 1,2-Dien-4-ynes
Gueugnot-Condon, Sylvie,Linstrumelle, Gerard
, p. 1851 - 1858 (2000)
The palladium-catalyzed reaction of propargyl halides, tosylates and acetates with terminal alkynes is reported. The best yields are obtained from propargyl chlorides and 1-alkynes (i) in the presence of amine (triethylamine, diisopropylamine) in benzene,
Intramolecular palladium(II)-catalyzed 1,2-addition to allenes
Jonasson,Horvath,Backvall
, p. 9600 - 9609 (2007/10/03)
Palladium(II)-catalyzed intramolecular 1,2-additions to allenes substituted with an internal nucleophile have been developed. Carboxylic acids, alcohols, N-substituted amides, and carbamates were used as internal nucleophiles in the palladium-catalyzed re
