79807-44-6Relevant academic research and scientific papers
SYNTHESIS AND REACTIONS OF PHENYLGLYOXAL ANILS
Prato, Maurizio,Quintily, Ugo,Scorrano, Gianfranco
, p. 405 - 412 (2007/10/02)
Contrary to previous reports, the reaction of anilines and phenylglyoxal in toluene affords the expected anil PhCO-CH=N-Ar, 1.In many cases it is more convenient to carry out the reaction in methanol where the methanol adduct of 1 forms, which may be better isolated, characterised and stored.Since the alcohol adduct is in equilibrium with free 1, it can be used for synthetic purposes as precursor of 1 as in hydrolysis, Diels-Alder, and other reactions initiated by nucleophilic attack on the carbon-nitrogen double bond.
Removal of Toluene-p-sulphonyl Groups from Sulphonamides. Part 5. Reactions of Phenylglyoxal Imines and some Tosylimines
McKay, William R.,Proctor, George R.
, p. 2443 - 2450 (2007/10/02)
Phenylglyoxal anil monomers have been shown to react with several nucleophilic reagents and the structures of the products have been elucidated.Various N-tosylarylimines also react with nucleophiles to give useful products.Phenacylimidates underwent cycloadditions with diphenylketen; such reactions gave complex results with phenacylimines, but the latter reacted with conjugated dienes in the presence of BF3 to give cycloaddition products in good yield.
