79823-72-6Relevant academic research and scientific papers
Condensations with Oxime O-Sulfonates, I. - Synthesis of 2-Amino-4,5-dihydro-4,5-diimino-1H-pyrrole-3-carboxylates
Kinast, Guenther
, p. 1561 - 1567 (2007/10/02)
The reaction of the oxime O-tosylates 1 with amidinoacetic acid esters 2 does not lead to the expected pyrazines 4, but rather to the novel 4,5-dihydro-1H-pyrrole-3-carboxylates 8 (= 2-pyrroline-3-carboxylates) by rearrangement via 7.The hydrolysis of the pyrroles 8 and their reactions with amines have been studied.
