79828-08-3Relevant academic research and scientific papers
(4+2)-CYCLOADDITIONS OF SUBSTITUTED ARENEDIAZOCYANIDES: A KINETIC STUDY OF A NEW DIENOPHILE
Gapinski, Duane P.,Ahern, Michael F.
, p. 3875 - 3878 (2007/10/02)
the rate constants of the (4+2)-cycloaddition reaction between substituted E-arenediazocyanides and 2,3-dimethyl-1,3-butadiene have been determined in several solvents.The reaction displays linear Hammett behavior; the data suggest a concerted reaction me
Phase-Transfer Synthesis of Arenediazocyanides and Synthesis of Arenediazosulfones from Arenediazonium Cations and the Formation of Reduced Pyridazines by 2 + 4 Cycloaddition Reactions
Ahern, Michael F.,Leopold, Ahuva,Beadle, James R.,Gokel, George W.
, p. 548 - 554 (2007/10/02)
The remarkably versatile arenediazonium cations are also convenient to use and nondangerous when utilized as the BF4 or PF6 salts.Arenediazonium compounds have recently been shown to undergo the 2 + 4 Diels-Alder cycloaddition, but the reaction is solvent
