79833-75-3Relevant academic research and scientific papers
Accurate Single-Molecule Kinetic Isotope Effects
Fu, Huanyan,Guo, Xuefeng,Guo, Yilin,Jia, Chuancheng,Li, Huiping,Li, Zhizhou,Liu, Zhirong,Liu, Zitong,Mo, Fanyang,Yang, Chen,Zhang, Deqing,Zhang, Lei,Zhou, Shuyao,Zhu, Wenguang,Zhu, Xin
supporting information, (2022/02/05)
An accurate single-molecule kinetic isotope effect (sm-KIE) was applied to circumvent the inherent limitation of conventional ensemble KIE by using graphene-molecule-graphene single-molecule junctions. In situ monitoring of the single-molecule reaction tr
One-pot synthesis of α-aminophosphonates via a cascade sequence of allylamine isomerization/hydrophosphonylation
Mao, Liu-Liang,Li, Chen-Chen,Yang, Qiang,Cheng, Ming-Xing,Yang, Shang-Dong
supporting information, p. 4473 - 4476 (2017/04/26)
A Rh/Ni-catalyzed cascade sequence of allylamine isomerization and hydrophosphonylation to synthesize α-aminophosphonates has been disclosed. The reaction, which not only allows the generation of widespread valuable α-aminophosphonates under simple system
Stereoselective isomerisation of N-Allyl aziridines into geometrically stable Z enamines by using rhodium hydride catalysis
Tsang, Derek S.,Yang, Sharon,Alphonse, France-Aimee,Yudin, Andrei K.
, p. 886 - 894 (2008/09/21)
In the presence of rhodium(I) hydride catalysts, tertiary N-allylamines are known to isomerise into E enamines. In contrast, we have recently found that N-allylaziridines isomerise to form Z enamines. On the basis of literature data, the most likely mecha
Synthesis of δ-L-α-aminoadipoyl-L-cysteinyl- D-allylglycine, and eight deuterated analogues, substrates for the investigation of the mechanism of action of isopenicillin n synthase
Baldwin, Jack E.,Bradley, Mark,Turner, Nicholas J.,Adlington, Robert M.,Pitt, Andrew R.,Sheridan, Helen
, p. 8203 - 8222 (2007/10/02)
The synthesis of δ-L-α-aminoadipoyl-L-cysteinyl-D-allylglycine (1a) from its component amino acids is described, along with the synthesis of eight analogues (1b-i) specifically deuterated at C-3 and/or C-5 of the allyglycine residue.
Base Catalysed Rearrangements Involving Ylide Intermediates. Part 12. The Preparation and Reactions of 2-Oxidoanilinium Ylides
Ollis, W. David,Sutherland, Ian O.,Thebtaranonth, Yodhathai
, p. 1981 - 1993 (2007/10/02)
2-Oxidoanilinium ylides (22) may be prepared from the corresponding quarternary salts (21) by reaction with aqueous sodium hydroxide.The ylides (22) rearrange on heating to give the products (23) of rearrangements which, on the basis of mixing exper
