79837-66-4Relevant academic research and scientific papers
Synthesis, Properties, and Light Fastness of Diaminomaleimide and Some of its Derivatives
Leismann, Hans,Marzolph, Gerhard,Scharf, Hans-Dieter,Behruzi, Massoud
, p. 2591 - 2615 (2007/10/02)
Reaction of ammonia with dichloromaleimide (3) yields the aminomaleimides 1 and 4, 2,3-dichloromaleamide (6), and 2,3-diaminofumaramide (2) depending on solvent, temperature, and pressure.The reactivity of the eneamino groups in 1 and 4 are remarkably different, 1 reacts like an amine while 4 resembles an amide.Interpretation of the ultraviolett and fluorescence spectra shows that 1, 4, and the acyl derivatives 13 - 15 can be classified as meropolar dyes.Light fastness values and fluorescence yields show a reverse correlation by change of solvent.Photochemical decomposition and fluorescence show a reactivity-selectivity correlation by variation of substituents at the double bond.
Acylation of Amines with Dichloromaleoyl Chloride
Bonse, Gerhard,Blank, Heinz Ulrich
, p. 1658 - 1664 (2007/10/02)
The reaction of dichloromaleoyl chloride (2) with ammonia in ether yields the ammonium salt of (Z)-2,3-dichloro-3-cyanoacrylic acid (6) and with aqueous ammonia the ammonium salt of (Z)-2-amino-3-chloro-3-cyanoacrylic acid (1).With primary aliphatic and aromatic amines dichloromaleamides 8 are obtained, the two chlorine atoms of which can be replaced with other amines to form after cis/trans isomerization diaminofumaramides 11.
