79884-27-8

Upstream product

• 51477-52-2 3β,17β-bis(tetrahydro-2-pyranyloxy)-5-androsten-16-one 
• 1159-66-6 3β,17β-dihydroxyandrost-5-en-16-one 
• 79884-10-9 15-hydroxymethylene-3β,17β-bis(tetrahydro-2-pyranyloxy)-5-androsten-16-one 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 79884-22-3 16β-acetoxy-3β,17β-bis(tetrahydro-2-pyranyloxy)-15α-tolylsulfonyloxymethyl-5-androstene 

Relevant academic research and scientific papers

Steroids, XL. - 15-(Hydroxymethyl)androstene and -estratriene Derivatives

15α-Hydroxymethyl-5-androstene-3β,16β,17β-triol (5d) and 16β-hydroxy-15α-(hydroxymethyl)estratriene derivatives 9 were prepared from the corresponding 15-hydroxymethylene-16-ketones 3 and 4.The configurations of the chiral centers were determined by means of chemical transformations and on the basis of spectroscopic data.The D-seco derivatives 6 and 8 were identified as the products of a fragmentation and a 1,3-dicarbonyl fission, respectively.