79902-99-1

Basic information

• Product Name: O-α-D-Glucopyranosyl-(1-3)-α,β-L-rhamnopyranose
• CAS NO: 79902-99-1
• Molecular Weight: 326.301
• Mol File: 79902-99-1.mol

Chemical Properties

• CAS DataBase Reference: O-α-D-Glucopyranosyl-(1-3)-α,β-L-rhamnopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: O-α-D-Glucopyranosyl-(1-3)-α,β-L-rhamnopyranose(79902-99-1)
• EPA Substance Registry System: O-α-D-Glucopyranosyl-(1-3)-α,β-L-rhamnopyranose(79902-99-1)

Safety Data

• Hazardous Substances Data: 79902-99-1(Hazardous Substances Data)

Upstream product

• 131328-60-4 Benzyl 2,4-di-O-benzyl-3-O-(2,4,6-tri-O-benzyl-α-D-glucopyranosyl)-α-L-rhamnopyranoside 
• 62774-11-2 Benzyl 2,4-di-O-benzyl-α-L-rhamnopyranoside 
• 128716-38-1 ethyl 3-O-allyl-2,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside 
• 131328-59-1 Benzyl 3-O-(3-O-allyl-2,4,6-tri-O-benzyl-α-D-glucopyranosyl)-2,4-di-O-benzyl-α-L-rhamnopyranoside 
• 73-34-7 L-rhamnose 
• 59-56-3 β-D-glucose 1-phosphate 

Relevant articles and documents

3-O-α-d-glucopyranosyl-L-rhamnose phosphorylase from Clostridium phytofermentans

We found an unreported activity of phosphorylase catalyzed by a protein (Cphy1019) belonging to glycoside hydrolase family 65 (GH65) from Clostridium phytofermentans. The recombinant Cphy1019 produced in Escherichia coli did not phosphorolyze α-linked glucobioses, such as trehalose (α1-α1), kojibiose (α1-2), nigerose (α1-3), and maltose (α1-4), which are typical substrates for GH65 enzymes. In reverse phosphorolysis, Cphy1019 utilized only l-rhamnose as the acceptor among various sugars examined with β-d-glucose 1-phosphate as the donor. The reaction product was determined to be 3-O-α-d-glucopyranosyl-l-rhamnose, indicating strict α1-3 regioselectivity. We propose 3-O-α-d-glucopyranosyl-l-rhamnose: phosphate β-d-glucosyltransferase as the systematic name and 3-O-α-d- glucopyranosyl-l-rhamnose phosphorylase as the short name for this novel GH65 phosphorylase.

Synthesis of structural elements of the capsular polysaccharides of Streptococcus pneumoniae types 6A and 6B

O-α-D-Glucopyranosyl-(1->3)-α,β-L-rhamnopyranose (15), O-α-D-galactopyranosyl-(1->3)-O-α-glucopyranosyl-(1->3)-α,β-L-rhamnopyranose (17), O-α-D-galactopyranosyl-(1->3)-O-α-D-glucopyranosyl-(1->3)-O-α-L-rhamnopyranosyl-(1->3)-D-ribitol (23), and O-α-D-gala