79917-39-8

Basic information

• Product Name: Pyrimidine, 2-nitroso- (9CI)
• Synonyms: Pyrimidine, 2-nitroso- (9CI)
• CAS NO: 79917-39-8
• Molecular Formula: C₄H₃N₃O
• Molecular Weight: 109.08612
• Product Categories: PYRIMIDINE
• Mol File: 79917-39-8.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Pyrimidine, 2-nitroso- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Pyrimidine, 2-nitroso- (9CI)(79917-39-8)
• EPA Substance Registry System: Pyrimidine, 2-nitroso- (9CI)(79917-39-8)

Safety Data

• Hazardous Substances Data: 79917-39-8(Hazardous Substances Data)

Upstream product

• 126382-48-7 2-Hydroxyaminopyrimidine 
• 75-18-3 dimethylsulfide 
• 54214-58-3 1,1-dimethyl-N-(pyrimidin-2-yl)-λ⁴-sulfanimine 

Downstream Products

• 79917-54-7 nitro-pyrimidine 
• 64233-24-5 1-methyl-6-phenylpteridine-2,4-dione 
• 79917-52-5 2-<(p-methoxyphenyl)azo>pyrimidine 
• 117782-40-8 N-phenylsulphonyl-N'-2-primidinyldiazene-N'-oxide 
• 117539-78-3 C₅H₃N₅O 

Relevant articles and documents

Catalytic Enantioselective Nitroso Diels-Alder Reaction

The nitroso Diels-Alder (NDA) reaction is an attractive strategy for the synthesis of 3,6-dihydro-1,2-oxazines and 1-amino-4-hydroxy-2-ene derivatives. Herein we report the Cu(I)-DTBM-Segphos catalyzed asymmetric intermolecular NDA reaction of variously substituted cyclic 1,3-dienes using highly reactive nitroso compounds derived from pyrimidine and pyridazine derivatives. In most of the cases studied, the cycloadducts were obtained in high yields (up to 99%) with very high regio-, diastereo-, and enantioselectivities (up to regioselectivity > 99:1, d.r. > 99:1, and >99% ee). As an application of this methodology, formal syntheses of conduramine A-1 and narciclasine were accomplished.

CATALTYTIC ASYMMETRIC HETERO DIELS-ALDER REACTION OF A HETEROAROMATIC C-NITROSO DIENOPHILE: A NOVEL METHOD FOR SYNTHESIS OF CHIRAL NON-RACEMIC AMINO ALCOHOLS

The present invention is directed to a catalytic asymmetric C-nitroso Diels-Alder reaction.

Conversion of a Primary Amino Group into a Nitroso Group. Synthesis of Nitroso-Substituted Heterocycles

2-Aminopyridine, 2-amino-4-methylpyridine, 1-aminoisoquinoline, 2-aminopyrimidine, and 2-aminopyrazine have been converted to the corresponding nitroso compounds by reaction with dimethyl sulfide and N-chlorosuccinimide, deprotonation of the resulting sul