79917-40-1Relevant academic research and scientific papers
Syntheses and biological activity studies of novel sterol analogs from nitroso diels-alder reactions of ergosterol
Yang, Baiyuan,Miller, Patricia A.,Moellmann, Ute,Miller, Marvin J.
supporting information; experimental part, p. 2828 - 2831 (2009/12/06)
A serles of novel sterol analogs was prepared using nitroso Dlels-Alder reactions with ergosterol. Most cycloaddltlon reactions proceeded In an excellent reglo- and stereoselective fashion. Further N-O bond cleavage of cycloadducts generated compounds with biological activity In PC-3 and MCF-7 cancer cell lines
Conversion of a Primary Amino Group into a Nitroso Group. Synthesis of Nitroso-Substituted Heterocycles
Taylor, Edward C.,Tseng, Chi-Ping,Rampal, Jang B.
, p. 552 - 555 (2007/10/02)
2-Aminopyridine, 2-amino-4-methylpyridine, 1-aminoisoquinoline, 2-aminopyrimidine, and 2-aminopyrazine have been converted to the corresponding nitroso compounds by reaction with dimethyl sulfide and N-chlorosuccinimide, deprotonation of the resulting sul
