79918-52-8Relevant academic research and scientific papers
Palladium-catalyzed allylation of α -nitroacetates with propynes
Yao, Shanshan,Liu, Jidan,Yang, Zhiyong,Gui, Qingwen,Chen, Xiang,Tan, Ze,Li, Ping
, p. 3165 - 3172 (2014)
A novel way to synthesize allylated α-nitroacetates under Pd catalysis has been described. Reactions of propynes with diverse α-nitroacetates in the presence of a catalytic amount of Pd(PPh3)4 and HOAc in 1,4-dioxane afforded the corresponding allylated products in good yields. Compared with other known methods, this method of synthesizing allylated α-nitroacetates generated no waste and needed neither a stoichiometric amount of base nor a leaving group.
