79919-62-3Relevant articles and documents
Synthesis of mesoporous metal complex-silica materials and their use as solvent-free catalysts
Linares, Noemi,Sepulveda, Angel E.,Pacheco, Maria C.,Berenguer, Jesus R.,Lalinde, Elena,Najera, Carmen,Garcia-Martinez, Javier
, p. 225 - 234 (2011)
Incorporation of various Pd(ii) complexes into the framework of MSU-X mesoporous silica has been achieved by co-condensation using a facile solvent-free one-pot synthesis. The use of ligands with triethoxysilyl terminal groups permitted the synthesis of t
Synthesis of Pd(II) organometal incorporated ordered Im3m mesostructural silica and its catalytic activity in a water-medium Sonogashira reaction
Zhu, Fengxia,Zhu, Lili,Sun, Xiaojun,An, Litao,Zhao, Pusu,Li, Hexing
, p. 4594 - 4599 (2014/11/08)
A novel and reusable Pd(ii) organometal functionalized SBA-16 catalyst was synthesized by the co-condensation of Pd[PPh2(CH2) 2Si(OCH2CH3)3]3Cl 2 and tetraethyl orthos
Sol-gel derived hybrid materials as heterogeneous catalysts for the synthesis of N,N-dimethylformamide from supercritical carbon dioxide
Kroecher, Oliver,Koeppel, Rene A.,Baiker, Alfons
, p. 1497 - 1498 (2007/10/03)
Hybrid materials derived from group VIII metal-chloro complexes of the type MCl2X2 (M = Pt, Pd), MClX3 (M = Rh, Ir) and especially RuCl2X3 [X = Ph2P(CH2)2Si(OEt)3, Me2P(CH2)2Si(OEt)3] by cocondensation with Si(OEt)4 via a sol-gel process are highly active heterogeneous catalysts for the synthesis of N,N-dimethylformamide (dmf) from CO2, H2 and dimethylamine under supercritical conditions, affording turnover numbers up to 110 800 at 100% selectivity.