799261-87-3

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 171357-22-5 (S,S)-1,2-di-tert-butylethane-1,2-diamine 
• 799261-61-3 (4S,5S)-4-tert-Butyl-5-methoxy-1-((1S,2R,4R)-2-methoxy-7,7-dimethyl-bicyclo[2.2.1]heptane-1-carbonyl)-3-(toluene-4-sulfonyl)-imidazolidin-2-one 
• 799261-59-9 (4S,5S)-4-tert-Butyl-5-methoxy-1-((1S,2R,4R)-2-methoxy-7,7-dimethyl-bicyclo[2.2.1]heptane-1-carbonyl)-imidazolidin-2-one 
• 799261-65-7 (4S,5S)-trans-1-p-tolylsulfonyl-4,5-di-tert-butyl-2-imidazolidinone 
• 799261-63-5 (4S,5S)-5-tert-Butyl-4-methoxy-1-(toluene-4-sulfonyl)-imidazolidin-2-one 

Relevant academic research and scientific papers

Chiral bis(N-sulfonylamino)phosphine- and TADDOL-phosphite-oxazoline ligands: Synthesis and application in asymmetric catalysis

A series of N,P-ligands has been prepared, containing a chiral oxazoline ring and as a second chiral unit a bis(N-sulfonylamino)phosphine group embedded in a diazaphospholidine ring or a cyclic phosphite group derived from TADDOL. These modular ligands are readily synthesized from chiral amino alcohols and chiral 1,2-diamines or TADDOLs. Palladium and iridium complexes derived from these ligands were found to be efficient catalysts for enantioselective allylic alkylation and olefin hydrogenation, respectively.

Enantioselective synthesis of (1S,2S)-1,2-di-tert-butyl and (1R,2R)-1,2-di-(1-adamantyl)ethylenediamines

The enantioselective synthesis of sterically congested C 2-symmetric 1,2-di-tert-butyl and 1,2-di-(1-adamantyl) ethylenediamines was successfully achieved starting from the simple heterocycle, 2-imidazolone. An enantioselective synthesis of ste