799278-89-0Relevant academic research and scientific papers
Proof of Concept Studies Directed Towards Designed Molecular Wires: Property-Driven Synthesis of Air and Moisture-Stable Polystannanes
Pau, Jeffrey,Lough, Alan J.,Wylie, R. Stephen,Gossage, Robert A.,Foucher, Daniel A.
, p. 14367 - 14374 (2017)
Polystannanes with azobenzene moieties designed to protect the Sn–Sn backbone from light- and moisture-induced degradation are described. The azo-stannyl precursor 3 (70 %) is converted in good yields (88–91 %) to the mono- (4), and dichlorostannanes (5),
Synthesis of a tin-functionalized cyclopentadiene derivative
Christoffers, Jens,Werner, Thomas,Baro, Angelika,Fischer, Peter
, p. 3550 - 3555 (2007/10/03)
A 3-tert-butyl-1-(stannylpropyl)-functionalized cyclopentadienyl ligand precursor 6 is readily available in 64% overall yield from allylic alcohol 1 by a three-step reaction sequence including Pd-catalyzed hydrostannylation with Ph3SnH. Treatment with FeCl2 and ZrCl4 · 2THF afforded corresponding ferrocene and zirconocene derivatives. Transmetallation of Sn-Ph with Li-Bu was observed under these reaction conditions by using BuLi as a base.
