79942-31-7Relevant academic research and scientific papers
Catalytic approach for the synthesis of bis-calixarenes
Agrawal,Bhatt
, p. 553 - 559 (2007)
Three new tail-to-tail linked biscalix[6]arenes joined via ether linkages have been synthesized. These bis calix[6]arenes have been characterized by 1H NMR, 13C NMR, and mass spectroscopy and elemental analysis. Copyright Taylor & Francis Group, LLC.
Stepwise Syntheses of o,o'-Methylene Bridged Cyclohexamers with p-Cresol and 4-tert-Butyl Phenol units. Comparison with Similarly Structured Hexanuclear Chainoligomers
Kaemmerer, Hermann,Happel, Guenter
, p. 759 - 768 (1981)
Two phenolic alcohols with six phenolic units in their molecules have been obtained by stepwise syntheses starting from simple phenolic derivatives.The phenolic alcohols were cyclized in a one step cyclization by boiling in a very diluted acetic acid solution.A two step cyclization of a phenolic alcohol with three phenolic units to a cyclohexamer proceeds only with poor yields.The cyclic compounds were compared with chainlike oligomers containing six phenolic units in their molecules. - Keywords: Chainlike phenol formaldehyde compounds; Cyclohexamers with phenolic units; Phenolic alcohols
Influence of base and solvent on the reaction between p-cresol and formaldehyde leading to p-methylcalix[n]arenes
Ostaszewski,Lipkowski,Jurczak
, p. 1053 - 1059 (2007/10/03)
Effects of solvent and base on the reaction of p-cresol with formaldehyde were studied using a liquid SIMS method. In all cases, complex mixtures of p-methylcalix[n]arenes were obtained and selectivities depended on the cation type and solvent used. Two pure products, p-methylcalix[7]arene and p-methylcalix[8]arene, were isolated.
