79950-44-0

Upstream product

• 3958-79-0 methyl 3,6-dioxocyclohexa-1,4-diene-1-carboxylate 
• 762-73-2 trimethyl(allyl)stannane 
• 79250-47-8 5-allyloxy-2-hydroxy-benzoic acid methyl ester 

Downstream Products

• 99668-96-9 3-allyl-2-methoxycarbonyl-1,4-benzoquinone 

Relevant academic research and scientific papers

Allylation of 2-Alkanoyl 1,4-Quinones with Allylsilanes and Allylstannanes. Efficient Synthesis of Pyranonaphthoquinone Antibiotics

Total syntheses of pyranonaphthoquinone antibiotics eleutherin, isoeleutherin, nanaomycin A, and deoxyfrenolicin are described.The crucial step in the route is a regioselective allylation of alkanoyl quinones with allylsilanes and allylstannanes.The allyl

Claisen Rearrangement of meta-Substituted Allyl Phenyl Ethers

Electron-releasing substituents at the 3-position of allyl phenyl ethers favour Claisen rearangement of the allyl group to the 6-position, whereas electron-acceptors favour migration to the 2-position. 2-Acylhydroquinone 4-allyl ethers yield, predominantly, the 3-allyl isomers, probably because internal hydrogen bonding confers naphthalenoid character on the aryl residue.