79950-44-0Relevant articles and documents
Allylation of 2-Alkanoyl 1,4-Quinones with Allylsilanes and Allylstannanes. Efficient Synthesis of Pyranonaphthoquinone Antibiotics
Uno, Hidemitsu
, p. 350 - 358 (2007/10/02)
Total syntheses of pyranonaphthoquinone antibiotics eleutherin, isoeleutherin, nanaomycin A, and deoxyfrenolicin are described.The crucial step in the route is a regioselective allylation of alkanoyl quinones with allylsilanes and allylstannanes.The allyl