79958-56-8Relevant academic research and scientific papers
Efficient Transformation of Trithio- and Triseleno-orthoesters into Ketene Dithio- and Diseleno-acetals
Nsunda, K. M.,Hevesi, L.
, p. 1000 - 1001 (2007/10/02)
Sequential treatment of trithio- and triseleno-orthoesters with a Lewis acid followed by a base leads to ketene dithio- and diseleno-acetals in good yield; SnCl4 or TiCl4 and (i-Pr)2EtN or Et3N are the most efficient reagents.
PREPARATION OF 3-HYDROXYL-VINYL SELENIDES AND 1,3-BIS(SELENO)-PROPENES
Renard, M.,Hevesi, L.
, p. 5939 - 5954 (2007/10/02)
Z and E 3-hydroxy-vinyl selenides can be prepared with very high stereoselectivity respectively by nucleophilic addition of selenolates to propargyl alcohols and by selenylation followed by LiAlH4 reduction of the same propargyl alcohols. 1,3-Bis(seleno)-
