79971-49-6Relevant articles and documents
Reaction of 1,1-dichloroethane with tellurium in the system hydrazine hydrate-potassium hydroxide
Levanova,Grabel'nykh,Kolesnikov,Klyba,Zhanchipova,Albanov,Russavskaya,Korchevin
experimental part, p. 988 - 992 (2011/02/26)
The reaction of 1,1-dichloroethane with tellurium in the system hydrazine hydrate-potassium hydroxide gave ethyltellanyl derivatives as a result of replacement of one chlorine atom in the substrate by tellurium, and of the other, by hydrogen. Probable mechanisms of reduction of the C-Cl bond and mass spectra of the products were considered. The mass spectra of ditelluroacetals revealed unusual rearrangement of the molecular ion, leading to the formation of Te-Te and new C-C bond.
