79990-35-5Relevant academic research and scientific papers
Borinic Acids via Direct Arylation of Amine-Borane Complexes: An Air- and Water-Stable Boron Source
Richard, Jimmy,Birepinte, Mélodie,Charbonnier, Jean Baptiste,Liautard, Virginie,Pinet, Sandra,Pucheault, Mathieu
, p. 736 - 744 (2017/02/15)
A synthesis of borinic acids and borinates was optimized using amine-borane complexes as a water and air insensitive borylating agent. The reaction operates under convenient conditions using a non-cryogenic temperature and with no flash chromatography, and it gives no boron impurities. The reaction proceeds through a tandem dehydrogenation-double addition mechanism.
CONTRIBUTIONS TO ORGANOBORON CHEMISTRY. XV. AMINODIPHENYLBORANES
Brown, Charles,Cragg, R. Harry,Miller, Tim J.,Smith, David O'N.
, p. 139 - 149 (2007/10/02)
The synthesis of a series of aminodiphenylboranes is reported together with the results of a detailed study of their 13C NMR spectra.All compounds exhibited peaks assignable to the carbon atom directly bonded to boron when run under appropriate conditions.The 13C spectra of primary aminodiphenylboranes provided further evidence for restricted rotation about the B-N bond.
