79991-72-3Relevant academic research and scientific papers
Synthesis of α-Chlorothiosulfenyl Chlorides. A New Class of Reactive Organosulfur Compounds
Still, Ian W. J.,Kutney, Gerald W.,McLean, David
, p. 555 - 560 (2007/10/02)
The reaction of various aromatic and suitably substituted aliphatic thiones with sulfur dichloride in dry carbon disulfide affords the corresponding α-chlorothiosulfenyl chlorides (R2C(Cl)SSCl), the first simple compounds of this type.Reaction of the α-chlorothiosulfenyl chlorides with triphenylphosphine regenerates the thiones, accompanied by the corresponding ketones.Possible mechanisms for these transformations are presented.
