80006-28-6Relevant academic research and scientific papers
Activation of Mono- and Di-nuclear Polyhydrides of Rhenium: Protonation, Solvation, and Oxidation
Allison, Joe D.,Walton, Richard A.
, p. 401 - 403 (1983)
Activation of the rhenium polyhydrides ReH5(PPh3)2L (L=monodentate ligand) and Re2H8(PPh3)4 has been achieved through their protonation (using HBF4), the formation of solvento-complexes, and their oxidation to reactive paramagnetic cations, strategies which have led to a range of novel species, including 2+, +, and t)2>+ together with their '17-electron' paramagnetic congeners.
