80018-91-3

Upstream product

• 68366-59-6 (2R,4aR,6S,7R,8aR)-6-methoxy-8-oxo-2-phenyl-7-phenylcarbonyloxyperhydropyrano[3,2-d][1,3]dioxine 
• 28642-64-0 methyl 2-O-benzoyl-4,6-di-O-benzylidene-α-D-glucopyranoside 
• 1589-82-8 phenylmagnesium bromide 
• 108-24-7 acetic anhydride 
• 80018-90-2 methyl 3-C-benzyl-4,6-O-benzylidene-α-D-allopyranoside 

Downstream Products

• 80018-92-4 methyl 2-O-acetyl-3-C-benzyl-4,6-O-benzylidene-3-deoxy-α-D-erythro-hex-3-enopyranoside 
• 80018-94-6 methyl 6-O-benzoyl-2,3-dideoxy-3-C-benzyl-α-D-glycero-hex-2-enopyranosid-4-ulose 
• 80018-93-5 methyl 3-C-benzyl-2,3-dideoxy-α-D-glycero-hex-2-enopyranosid-4-ulose 

Relevant academic research and scientific papers

THE SYNTHESES OF SOME METHYL 3-C-ALKYL-2,3-DIDEOXY-α-D-glycero-HEX-2-ENOPYRANOSID-4-ULOSES

A general synthetic route to the title compounds is outlined which involves: (a) the Grignard reduction of methyl 2-O-benzoyl-4,6-O-benzylidene-α-D-ribo-hexopyranosid-3-ulose; (b) the dehydration of the derived methyl 2-O-acetyl-3-C-alkyl-4,6-O-benzyliden