800391-70-2Relevant academic research and scientific papers
The reaction of butatrienolates with aldehydes for the syntheses of α-vinylidene acylsilanes
Shibata, Takanori,Takami, Kyoko,Arai, Yoshikazu,Tsachikaina, Kyoji,Maekawa, Shunsuke
, p. 1937 - 1938 (2004)
Lithium butatrienolates were prepared in situ by the 1,4-elimination from 2-butynyl trimethylsilyl ethers along with a retro-Brook rearrangement. The addition reaction of the enolates with the aldehydes afforded β-hydroxy-α-vinyl-idene acylsilanes.
