80048-28-8Relevant academic research and scientific papers
Aminoethynyl Metallations, 16. - Synthesis and Reactivity of Ynamines with a Thiocarboxamide Group in the β-Position
Himbert, Gerhard
, p. 2371 - 2382 (2007/10/02)
By reaction of the aminoacetylides 2 with alkyl and aryl isothiocyanates 3 the 3-aminopropiolthioamides 5 are formed.Benzyl and allyl bromides 6 alkylate these ynamines at the sulfur atom thus forming the S-alkyl 3-aminopropiolthioimidates 7.Hydrogen sulf
Aminoethynyl Metallations, 10. - Synthesis and Reactivity of 3-Aminopropiolamides
Himbert, Gerhard,Schwickerath, Willi
, p. 1844 - 1864 (2007/10/02)
The 3-aminopropiolamides 5 can be synthesized on two different ways: A) by reaction of the β-stannylated ynamines 1 with aryl isocyanates 2 (R4 = Ar) and by hydrolysis of the obtained stannyl 3-aminopropiolimidates 3; B) by direct acting of the
