80053-85-6

Basic information

• Product Name: 2-Azabicyclo[3.2.0]heptane-5-carboxylic acid, 7-ethenyl-3,4-dioxo-1-phenyl-7-[(trimethylsilyl)oxy]-, ethyl ester
• CAS NO: 80053-85-6
• Molecular Formula: C20H25NO5Si
• Molecular Weight: 387.508
• Mol File: 80053-85-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Azabicyclo[3.2.0]heptane-5-carboxylic acid, 7-ethenyl-3,4-dioxo-1-phenyl-7-[(trimethylsilyl)oxy]-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Azabicyclo[3.2.0]heptane-5-carboxylic acid, 7-ethenyl-3,4-dioxo-1-phenyl-7-[(trimethylsilyl)oxy]-, ethyl ester(80053-85-6)
• EPA Substance Registry System: 2-Azabicyclo[3.2.0]heptane-5-carboxylic acid, 7-ethenyl-3,4-dioxo-1-phenyl-7-[(trimethylsilyl)oxy]-, ethyl ester(80053-85-6)

Safety Data

• Hazardous Substances Data: 80053-85-6(Hazardous Substances Data)

Upstream product

• 38053-91-7 2-trimethylsilyloxy-1,3-butadiene 
• 59046-34-3 3-ethoxycarbonyl-2-phenyldioxopyrroline 

Downstream Products

• 140700-57-8 (1S,3S,6R,7R,9S)-6-Hydroxy-9-methanesulfonyloxy-5-oxo-3-phenyl-4-aza-tricyclo[4.3.0.0^3,7]nonane-7-carboxylic acid ethyl ester 
• 140700-57-8 (1S,3S,6R,7R,9R)-6-Hydroxy-9-methanesulfonyloxy-5-oxo-3-phenyl-4-aza-tricyclo[4.3.0.0^3,7]nonane-7-carboxylic acid ethyl ester 
• 89877-48-5 (3aS,7aR)-2-Ethoxy-3,5-dioxo-7a-phenyl-3,4,5,6,7,7a-hexahydro-indole-3a-carboxylic acid ethyl ester 
• 80053-95-8 (1S,3R,6S,7S)-6-Hydroxy-5,9-dioxo-3-phenyl-4-aza-tricyclo[4.3.0.0^3,7]nonane-7-carboxylic acid ethyl ester 
• 80053-90-3 (3aS,7aR)-2,3,5-Trioxo-7a-phenyl-octahydro-indole-3a-carboxylic acid ethyl ester 
• 59046-62-7 dl-(1R*,6S*)-1-ethoxycarbonyl-6-phenyl-7-azabicyclo<4.3.0>non-3-ene-8,9-dione 
• 80053-95-8 (3R,6S,7S)-6-Hydroxy-5,9-dioxo-3-phenyl-4-aza-tricyclo[4.3.0.0^3,7]nonane-7-carboxylic acid ethyl ester 
• 88461-30-7 (1R,3S,6R,7S)-3-Hydroxy-4,9-dioxo-6-phenyl-5-aza-tricyclo[4.3.0.0^3,7]nonane-7-carboxylic acid ethyl ester 
• 59046-34-3 3-ethoxycarbonyl-2-phenyldioxopyrroline 
• 80053-88-9 (3aS,7aR)-2,3-Dioxo-7a-phenyl-5-trimethylsilanyloxy-1,2,3,4,7,7a-hexahydro-indole-3a-carboxylic acid ethyl ester 
• 89877-47-4 (1S,3R,6S,7R)-4-Ethoxy-3-hydroxy-9-oxo-6-phenyl-5-aza-tricyclo[4.3.0.0^3,7]non-4-ene-7-carboxylic acid ethyl ester 

Relevant articles and documents

Dioxopyrroline. L. Skeletal rearrangements of 7-vinyl-7-trimethylsilyloxy-5-ethoxycarbonyl-1-phenyl-2-azabicyclo[3.2. 0]heptane-3,5-diones under thermal, basic, and acidic conditions

The oxyvinylcyclobutanes (2), photoadducts of the dioxopyrrolines (1) to trimethylsilyloxybutadienes, undergo two different types of skeletal rearrangements depending on the reaction conditions. Thermolysis of 2 caused expansion of the cyclobutane ring by

2-AZABICYCLOHEPTANE-3,4-DIONES (6) A NOVEL METHOD OF REGIO-CONTROLLED SYNTHESIS OF FUNCTIONALIZED HYDROINDOLES AND ERYTHRINAN DERIVATIVES

A regio-controlled synthesis of functionalized hydroindoles from a Δ2-pyrrolinedione and its application to the synthesis of erythrinan skeleton were described.The method is to construct with photocycloaddition of a trimethylsilyloxybutad