80058-84-0Relevant articles and documents
New Bromine-Containing Bis(arylimino)acenaphthenes and Related Metal Complexes
Baranov, E. V.,Dodonov, V. A.,Fedushkin, I. L.,Koptseva, T. S.,Makarov, V. M.,Skatova, A. A.,Sokolov, V. G.
, p. 215 - 223 (2020)
Abstract: The condensation reactions of 5-bromoacenaphthenequinone with 2,6-diisopropylaniline and 4?bromo-2,6-di-iso-propylaniline afford new mono- and tribromosubstituted bis(arylimino)acenaphthenes: 1,2-bis[(2,6-diisopropylphenyl)imino]-5-bromacenaphthene (Dpp-Br-Bian) (L1) and 1,2-bis[(4-bromo-2,6-diisopropylphenyl)imino]-5-bromacenaphthene (p-Br-Dpp-Br-Bian) (L2), respectively. Compounds L1 and L2 act as neutral ligands in the [(Dpp-Br-Bian)ZnCl2] (I), [(p-Br-Dpp-Br-Bian)AlCl3] (III), and [(p-Br-Dpp-Br-Bian)GaCl3] (IV) complexes synthesized by the reactions of free diimines with the corresponding metal chlorides. The reaction of the known dibromosubstituted derivative 1,2-bis[(4-bromo-2,6-di-iso-propylphenyl)iminoacenaphthene (p-Br-Dpp-Bian) (L3) with copper(I) chloride also affords complex [(p-Br-Dpp-Bian)CuCl] (II) with the neutral diimine ligand. New compounds L1, L2, and I–IV are characterized by NMR, IR spectroscopy, and elemental analysis. The molecular structure of complex I is determined by X-ray structure analysis.
Synthesis method of diafenthiuron impurities A and B
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Paragraph 0037-0039, (2021/08/06)
The invention provides a preparation method of the diafenthiuron impurities A and B. 2, 6-isopropylaniline, phenol, triphosgene, tert-butylamine and tert-butyl formamidine hydrochloride are used as raw materials, a material basis is provided for normatively researching the impurities, and the method can also be used for qualitative and quantitative analysis of the impurities in diafenthiuron production. And the impurities are controlled within a safe and reasonable limit range, so that the quality standard of the diafenthiuron can be improved, and important guiding significance is provided for safe medication of the masses.
Development of effective bidentate diphosphine ligands of ruthenium catalysts toward practical hydrogenation of carboxylic acids
Saito, Susumu,Wen, Ke,Yoshioka, Shota
supporting information, p. 1510 - 1524 (2021/06/18)
Hydrogenation of carboxylic acids (CAs) to alcohols represents one of the most ideal reduction methods for utilizing abundant CAs as alternative carbon and energy sources. However, systematic studies on the effects of metal-to-ligand relationships on the catalytic activity of metal complex catalysts are scarce. We previously demonstrated a rational methodology for CA hydrogenation, in which CA-derived cationic metal carboxylate [(PP)M(OCOR)]+ (M = Ru and Re; P = one P coordination) served as the catalyst prototype for CA self-induced CA hydrogenation. Herein, we report systematic trial- and-error studies on how we could achieve higher catalytic activity by modifying the structure of bidentate diphosphine (PP) ligands of molecular Ru catalysts. Carbon chains connecting two P atoms as well as Ar groups substituted on the P atoms of PP ligands were intensively varied, and the induction of active Ru catalysts from precatalyst Ru(acac)3 was surveyed extensively. As a result, the activity and durability of the (PP)Ru catalyst substantially increased compared to those of other molecular Ru catalyst systems, including our original Ru catalysts. The results validate our approach for improving the catalyst performance, which would benefit further advancement of CA self-induced CA hydrogenation.