80077-62-9Relevant academic research and scientific papers
CYCLOADDITION OF FUNCTIONALLY SUBSTITUTED AZIDES TO ACETYLENIC ALCOHOLS
Tikhonova, L. G.,Serebryakova, E. S.,Maksikova, A. V.,Chernysheva, G. V.,Vereshchagin, L. I.
, p. 1244 - 1248 (2007/10/02)
The corresponding hydroxymethyl-1,2,3-triazoles were obtained by the reaction of monosubstituted and disubstituted acetylenic alcohols with a wide range of organic azides.It was shown that the reaction of azidoacetic acid with acetylenic keto alcohols is accompanied by the formation of triazolooxazines; sterically hindered azides do not add to the acetylenic carbinols; azido ketones are converted in the reaction into urethane and carbanilide.
