80091-08-3Relevant academic research and scientific papers
Generation of iminyl copper species from α-azido carbonyl compounds and their catalytic C-C bond cleavage under an oxygen atmosphere
Chiba, Shunsuke,Zhang, Line,Ang, Gim Yean,Hui, Benjamin Wei-Qiang
supporting information; experimental part, p. 2052 - 2055 (2010/07/04)
Figure presented A copper-catalyzed reaction of α-azidocarbonyl compounds under an oxygen atmosphere is reported where nitriles are formed via C-C bond cleavage of a transient iminyl copper intermediate. The transformation is carried out by a sequence of denitrogenative formation of iminyl copper species from α-azidocarbonyl compounds and their C-C bond cleavage, where molecular oxygen (1 atm) is a prerequisite to achieve the catalytic process and one of the oxygen atoms of O2 was found to be incorporated into the β-carbon fragment as a carboxylic acid.
PREPARATION OF α-BROMOESTERS VIA THE HALF ESTERS OF MALONIC ACIDS A NOVEL METHOD FOR RAPID DECARBOXYLATION UNDER MILD CONDITIONS
Goel, O. P.,Krolls, U.
, p. 163 - 166 (2007/10/02)
α-Bromomalonic acid half esters were prepared in high yield and found to be rapidly decarboxylated to α-bromoesters under mild conditions using lithium carbonate in refluxing tetrahydrofuran.
