80091-08-3

Basic information

• Product Name: BENZENEPENTANOIC ACID,A-BROMO-,ETHYL ESTER
• Synonyms: BENZENEPENTANOIC ACID,A-BROMO-,ETHYL ESTER;A-BroMobenzenepentanoic acid ethyl ester;BENZENEPENTANOIC ACID,α-BROMO-,ETHYL ESTER
• CAS NO: 80091-08-3
• Molecular Formula: C₁₃H₁₇BrO₂
• Molecular Weight: 285.18
• Mol File: 80091-08-3.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: BENZENEPENTANOIC ACID,A-BROMO-,ETHYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: BENZENEPENTANOIC ACID,A-BROMO-,ETHYL ESTER(80091-08-3)
• EPA Substance Registry System: BENZENEPENTANOIC ACID,A-BROMO-,ETHYL ESTER(80091-08-3)

Safety Data

• Hazardous Substances Data: 80091-08-3(Hazardous Substances Data)

Upstream product

• 17734-38-2 ethyl 5-phenylpentanoate 
• 85969-99-9 2-Bromo-2-(3-phenyl-propyl)-malonic acid monoethyl ester 
• 64-17-5 ethanol 
• 84299-75-2 2-bromo-5-phenyl-valeric acid 

Downstream Products

• 1221966-48-8 ethyl 2-azido-5-phenylpentanoate 
• 856338-87-9 β-dimethylamino-ethyl-ε-phenyl-n-amyl alcohol 

Relevant articles and documents

Generation of iminyl copper species from α-azido carbonyl compounds and their catalytic C-C bond cleavage under an oxygen atmosphere

Figure presented A copper-catalyzed reaction of α-azidocarbonyl compounds under an oxygen atmosphere is reported where nitriles are formed via C-C bond cleavage of a transient iminyl copper intermediate. The transformation is carried out by a sequence of denitrogenative formation of iminyl copper species from α-azidocarbonyl compounds and their C-C bond cleavage, where molecular oxygen (1 atm) is a prerequisite to achieve the catalytic process and one of the oxygen atoms of O2 was found to be incorporated into the β-carbon fragment as a carboxylic acid.