80094-07-1Relevant articles and documents
ORGANOPHOSPHORUS COMPOUNDS, XXXII THE REACTION OF ALKYL PHOSPHITES WITH 1-(DIPHENYLMETHYLENE)-2(1H)- AND 4-(DIPHENYLMETHYLENE)-1(4H)-NAPHTHALENONES
Sidky, M. M.,El-Kateb, A. A.,Hennawy, I. T.
, p. 343 - 348 (2007/10/02)
1-(Diphenylmethylene)-2(1H)-naphthalenone (1) reacts with trialkyl phosphites to give the corresponding 1,2-dihydro-2-alkoxy-1,1-diphenylnaphth-oxaphosphole-2-oxides (3a-c).The latter compounds are equally obtained by the reaction of dialkyl phosphites with 1.A mechanism for this reaction is presented which accounts for the experimental results.On the other hand, 4-(diphenylmethylene)-1(4H)-naphthalenone (2) reacts only with dialkyl phosphites to give dialkyl-phosphonates (9a-c).Structural assignments are based on analytical, chemical and spectroscopic evidence.