80123-07-5Relevant academic research and scientific papers
Characteristics of retention and enthalpies of sorption from the gas phase of esters of trimethylolpropane and С2–С5 acids on DB-1 stationary phase
Krasnykh,Aleksandrov, A. Yu.,Sokolova,Levanova
, p. 398 - 402 (2017/02/26)
Characteristics of retention and their temperature dependences, along with the thermodynamic characteristics of sorption on DB-1 nonpolar phase, are determined in the temperature range of 220–280°C for 21 mono-, di-, and trisubstituted esters of trimethylolpropane and monobasic acids with a variety of structures containing from 2 to 6 carbon atoms.
Zirconium phenyl phosphonate phosphite as a highly active, reusable, solid acid catalyst for producing fatty acid polyol esters
Varhadi, Poonam,Kotwal, Mehejabeen,Srinivas
, p. 129 - 136 (2013/07/26)
The application of zirconium phenyl phosphonate phosphite (ZrPP) as a solid acid catalyst for producing polyol esters by esterification of glycerol or trimethylolpropane with a fatty acid (C8-C18.1) is reported for the first time. ZrPP exhibits high catalytic activity and in particular, (di + tri) esters selectivity (92.3 mol%). These esters of polyols are known for their application as biolubricants. The catalyst prepared using phosphorous acid to phenyl phosphonic acid molar ratio of 3:1 was found superior. The influence of process parameters on activity and selectivity of the catalyst was investigated. ZrPP was reusable in at least three recycling experiments. Hydrophobicity due to exposed phenyl groups on the surface is the possible cause for superior esterification activity of this novel, solid catalyst.
