80127-54-4

Upstream product

• 60656-87-3 benzyloxyacetoaldehyde 

Downstream Products

• 80127-62-4 (2R,6R)-2-Benzyloxymethyl-6-methoxy-3,6-dihydro-2H-pyran 
• 80127-56-6 (2S,3S,4S,6S)-6-Benzyloxymethyl-tetrahydro-pyran-2,3,4-triol 
• 80127-56-6 (2R,3S,4S,6S)-6-Benzyloxymethyl-tetrahydro-pyran-2,3,4-triol 
• 80127-55-5 Acetic acid (2R,4R)-2-benzyloxymethyl-3,4-dihydro-2H-pyran-4-yl ester 
• 80127-57-7 Acetic acid (2S,3R,4R,6R)-3,4-diacetoxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl ester 

Relevant academic research and scientific papers

Preparation and reactions of 2-allyl-5-deoxymannose derivatives

Reaction of Danishefsky diene with benzyloxyethanal led to a pyrone which was transformed in 4-6 steps to different 5-deoxymannose derivatives, useful intermediates for the synthesis of natural product such as hemibrevetoxin.

Preparation of (+/-)-1-Allyl-4-deoxy Mannose Derivatives

Preparation of 4-deoxy mannose intermediates, useful for the synthesis of hemibrevetoxin is reported by a short reaction pathway. - Keywords: hemibrevetoxin; hetero Diels-Alder; allylation; iodoetherification; 4-deoxy mannose

Synthesis of C-disaccharides via glucal dimerisation

Treatment of 3-O-acetyl glucal and related species with acetylperchlorate provides good yields of the corresponding C-disaccharides with a high degree of stereocontrol at the new C-C bond. Copyright (C) 1996 Elsevier Science Ltd.