80137-05-9Relevant academic research and scientific papers
IRON CARBONYL COMPLEXATION OF DITHIOESTERS. FORMATION OF A CHIRAL CARBON CENTER ?-BONDED TO AN IRON ATOM
Benoit, Alain,Marouille, Jean-Yves Le
, p. C67 - C70 (2007/10/02)
Dithioesters react with diiron nonacarbonyl to afford binuclear complexes resulting from coordination of the carbon-sulfur double bond to the two iron atoms and donation of two electrons from the S-alkyl group to one iron center.This novel mode of complexation creates a carbon-iron single bond and a chiral center at the carbon atom bonded to the metal, as shown by the spectroscopic studies and by a X-ray structure determination.
