80137-71-9

Upstream product

• 7294-50-0 tri-o-tolylboroxine 
• 107-21-1 ethylene glycol 

Downstream Products

• 3917-57-5 N,N-dimethyl-2-(2-methylphenyl)ethanamide 
• 5080-10-4 2,4'-(ethane-1,1-diyl)bis(methylbenzene) 
• 1250907-29-9 (E)-6-(o-tolyl)hex-5-en-1-yl acetate 
• 1304616-29-2 ETM₂ 
• 1236889-29-4 (E)-1-methyl-2-(4-phenylbut-3-en-2-yl)benzene 
• 80137-75-3 2-{2-(bromomethyl)phenyl}-1,3,2-dioxaborolane 

Relevant academic research and scientific papers

Aerobic alcohol oxidation coupled to palladium-catalyzed alkene hydroarylation with boronic esters

(Chemical Equation Presented) An oxidation exercise: An aerobic alcohol oxidation coupled with a regioselective palladium-catalyzed reductive functionalization of styrenes and arylboronic esters has been developed (see scheme). The mechanism is thought to proceed by initial oxidation of the solvent to generate a PdII-hydride species, which subsequently reacts with the alkene and arylboronic ester to ultimately generate a new C-C bond.

Fast Thermal Breaking and Formation of a B - N Bond in 2-(Aminomethyl)benzeneboronates

The title compounds 1 to 6 (Table 1) are shown by 1H, 11B, and 15N NMR shifts to form an intramolecular B-N bond which, according to 1H and 13C NMR, is frequently broken (ΔGc* = 40 to 54 kJ/mol, Table 2) and re-formed.