80188-57-4Relevant academic research and scientific papers
REACTIONS OF TITANOCENE ALLYLS
Klei, E.,Teuben, J.H.,De Liefde Meijer, H.J.,Kwak, E.J.,Bruins, A.P.
, p. 327 - 339 (1982)
Cp2Tiη3-allyl and Cp2Tiη3-1-methylallyl react with carbon dioxide, phenylisocyanate, benzalaniline, acetone and acetonitrile to give insertion products which are formed via allyl migration.Normal insertion is observed with 2,6-xylylisocyanide.C
Titanium-promoted Allyl Transfer to Carbon Monoxide and Other Unsaturated Molecules
Klei, Bert,Teuben, Jan H.,Meijer, Henk J. de Liefde
, p. 342 - 344 (2007/10/02)
Carbonylation of Cp2Ti-(?-allyl) yields Cp2Ti(CO)2 and triallylmethanol; reactions of Cp2Ti-(?-allyl) and Cp2Ti-(?-1-methylallyl) with other ligands proceed via insertion or allyl-elimination pathways.
