80206-52-6Relevant academic research and scientific papers
One-Pot Nonphotochemical Synthesis of Dewar Pyridones from Alkynes and Isocyanates
Hogeveen, H.,Kok, D. M.
, p. 997 - 1001 (1982)
A one-pot synthesis of substituted 3-oxo-2-azabicyclohex-5-enes (Dewar pyridones) from alkynes, aluminum halides, and isocyanates is described.The mechanism of the reaction of isocyanates with the intermediate aluminum halide ? complexes of cyclobutadienes is discussed on the basis of the substitution pattern of the obtained bicyclic products.The thermal and acid-promoted reactions of some of the compounds are reported.
