80229-11-4Relevant academic research and scientific papers
RING EXPANSIONS IN CARBOHYDRATE CHEMISTRY: gem-AZOACETATES
Tronchet, Jean M.J.,Tronchet, Jeannine F.,Rachidzadeh, Faranak,Barbalat-Rey, Francoise
, p. 97 - 114 (2007/10/02)
On treatment with lead tetraacetate, blocked furanos-3-ulose and furanos-3-uloside p-nitrophenylhydrazones afforded the corresponding "gem-azoacetates".The reaction was not stereospecific, except when the starting hydrazone was blocked by a 1,2-O-isopropy
HYDROGENOLYSIS OF 3,5-O-BENZYLIDENE ACETALS WITH THE LiAlH4-AlCl3 REAGENT IN METHYL D-XYLOFURANOSIDES
Liptak, Andras,Neszmelyi, Andras,Kovac, Pavol,Hirsch, Jan
, p. 2379 - 2382 (2007/10/02)
The hydrogenolysis of methyl 3,5-O-benzylidene-α- and -β-D-xylofuranoside derivatives with the LiAlH4-AlCl3 reagent gave 5-benzyl ethers as main products.In some cases the attack of the reagent occured at the ring oxygen of the furanoside skeleton to yiel
