80234-08-8Relevant academic research and scientific papers
PHOTOCHEMICAL AROMATIC HYDROXYLATION BY AROMATIC AMINE N-OXIDES: REMARKABLE SOLVENT EFFECT ON NIH-SHIFT
Ogawa, Yuji,Iwasaki, Shigeo,Okuda, Shigenobu
, p. 3637 - 3640 (1981)
Photooxygenations of 4-(2)H-anisole (3) and o-xylene (5) by 3-methylpyridazine 2-oxide (1) or pyridine 1-oxide (2) were studied in a variety of solvents at varying irradiation temperatures.Remarkable solvent effect on NIH-shift coupled with their hydroxylation processes was observed.
Oxygen atom transfer from carbonyl oxide to alkane catalyzed by metalloporphyrin
Haranaka, Masayuki,Hara, Akiko,Ando, Wataru,Akasaka, Takeshi
body text, p. 3585 - 3587 (2009/09/28)
The reaction of singlet oxygen with diazofluorene in the presence of metalloporphyrin caused oxidation of hydrocarbons as well as sulfide and anisol in substantial yields. The active oxidizing species is probably a high valency metal oxo species(M{double bond, long}O(porph)Cl) generated by an oxygen transfer from carbonyl oxide intermediate to M(porph)Cl.
HYDROXYLATION OF BENZENES INVOLVING THE NIH SHIFT UTILIZING ELECTRONIC MODEL COMPOUND FOR MONOOXYGENASES
Kojo, Shosuke,Fukunishi, Koushi
, p. 1707 - 1710 (2007/10/02)
The reaction of anisole-4-(2)H or toluene-4-(2)H with 2-hydroperoxyhexafluoro-2-propanol gave corresponding phenols involving the NIH shift, the extent of which was 57percent and 51percent respectively.These values were very close to those of cytochrome P450.
ON THE MECHANISM OF AROMATIC HYDROXYLATION BY O(3P) ATOMS
Zadok, Elazor,Mazur, Yehuda
, p. 4955 - 4958 (2007/10/02)
It is shown that O(3P) oxidation of aromatic compounds in the liquid phase leading to phenols may involve the intermediacy of triplet diradicals
