80239-19-6Relevant academic research and scientific papers
2-ARYL-λ3-ARSENINE, 2,6-DIARYL-λ3-ARSENINE, 2-ARYL-4-R-λ3 ARSENINE UND 2,4,6-TRIARYL-λ3-ARSENINE DURCH 4-HYDROXY-1,4-DIHYDRO-ARSENIN ARSENIN-UMLAGERUNG
Maerkl, G.,Bergbauer, A.,Rampal, J. B.
, p. 4079 - 4082 (2007/10/02)
The title compounds, mono-,di- and trisubstituted λ3-arsenins, are obtained by treatment of 1-aryl-4-hydroxy-1,4-dihydroarsenins with acid.
Synthesis of 2-Aryl-(2-R)-arsenines by Cyclohexadienol -> Arsabenzene Rearrangement
Maerkl, Gottfried,Liebl, Rainer,Baier, Horst
, p. 1610 - 1632 (2007/10/02)
KOH/crown-6 phase-transfer catalyzed addition of arylarsines (phenylarsine, p-tolylarsine) to the (3-R)-3-methoxy-1,4-pentadiynes 13 yields the cis/trans isomeric 1-aryl-1,4-dihydro-(4-R)-4-methoxyarsenines, the 1H-NMR- and 13C-NMR spectra of which ar
