80255-08-9Relevant academic research and scientific papers
32. 2'-Nitro-2'-propen-1'-yl 2,2-Dimethylpropanoate (NPP), A Multiple Coupling Reagent
Seebach, Dieter,Knocherl, Paul
, p. 261 - 283 (2007/10/02)
The title compound 1 (NPP) is prepared from formaldehyde, nitromethane, and pivaloyl chloride.It is shown to be a versatile nitroallylating reagent combining with nucleophiles as different as anilines, indoles, enolates, and organolithium compounds.This i
NITROALLYLATION OF HIGHLY REACTIVE ORGANOLITHIUM COMPOUNDS BY 2-NITRO-3-PIVALOYLOXI-1-PROPENE (NPP)
Knochel, Paul,Seebach, Dieter
, p. 3223 - 3226 (2007/10/02)
The nitroolefin 1 (NPP) efficiently transfers a 2-nitroallyl group even to the most reactive nucleophilic centres of organolithium reagents to give the products of type 2 listed in the table.
