80279-07-8

Basic information

• Product Name: Silane, [(1E)-1-ethyl-1-butenyl]dimethylphenyl-
• CAS NO: 80279-07-8
• Molecular Formula: C14H22Si
• Molecular Weight: 218.414
• Mol File: 80279-07-8.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Silane, [(1E)-1-ethyl-1-butenyl]dimethylphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(1E)-1-ethyl-1-butenyl]dimethylphenyl-(80279-07-8)
• EPA Substance Registry System: Silane, [(1E)-1-ethyl-1-butenyl]dimethylphenyl-(80279-07-8)

Safety Data

• Hazardous Substances Data: 80279-07-8(Hazardous Substances Data)

Upstream product

• 185844-36-4 (Z)-1-[dimethyl(phenyl)silyl]but-1-enethiol 
• 120627-94-3 1-(Dimethyl-phenyl-silanyl)-butan-1-one 
• 928-49-4 hex-3-yne 
• 768-33-2 phenyldimethylsilyl chloride 
• 766-77-8 Dimethylphenylsilane 
• 925-90-6 ethylmagnesium bromide 
• 185844-38-6 Dimethyl-((Z)-1-methylsulfanyl-but-1-enyl)-phenyl-silane 
• 3839-31-4 dimethyl(phenyl)silyllithium 

Relevant articles and documents

Rhodium-catalyzed hydrosilylation of internal alkynes with silane reagents bearing heteroatom substituent. Studies on the regio-/stereochemistry and transformation of the produced alkenylsilanes by rhodium-catalyzed conjugate addition

Rhodium-catalyzed hydrosilylation of internal alkynes furnished (E)-1,2-disubstituted alkenylsilanes. The obtained alkenylsilane was subjected to reaction with α,β-unsaturated carbonyl compounds in the presence of a rhodium catalyst to undergo conjugate a

A recyclable and reusable K2PtCl4/Xphos-SO3Na/PEG-400/H2O system for highly regio- and stereoselective hydrosilylation of terminal alkynes

K2PtCl4/Xphos-SO3Na in a mixture of poly(ethylene glycol) (PEG-400) and water is shown to be a highly regio- and stereoselective catalyst for the hydrosilylation of terminal alkynes with hydrosilanes. The reaction could be conducted under mild conditions, yielding a variety of functionalized β-(E)-vinylsilanes in good to excellent yields with a total β-(E)-selectivity. The isolation of the products is readily performed by extraction with cyclohexane and more importantly, both expensive K2PtCl4 and Xphos-SO3Na in a PEG-400/H2O system could be easily recycled and reused at least eight times without any loss of catalytic activity.

Silylzincation of carbon-carbon multiple bonds revisited

The first investigation of the copper-catalyzed silylzincation of alkynes as well as a diene and styrene using bis(triorganosilyl) zinc reagents led to the development of an efficient procedure and the disclosure of an unexpected bissilylation and unfores