80279-09-0

Basic information

• Product Name: (E)-3-dimethyl(phenyl)silyl-4-methylhex-3-ene
• CAS NO: 80279-09-0
• Molecular Weight: 232.441
• Mol File: 80279-09-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-3-dimethyl(phenyl)silyl-4-methylhex-3-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-dimethyl(phenyl)silyl-4-methylhex-3-ene(80279-09-0)
• EPA Substance Registry System: (E)-3-dimethyl(phenyl)silyl-4-methylhex-3-ene(80279-09-0)

Safety Data

• Hazardous Substances Data: 80279-09-0(Hazardous Substances Data)

Upstream product

• 928-49-4 hex-3-yne 
• 3839-31-4 dimethyl(phenyl)silyllithium 
• 74-88-4 methyl iodide 

Relevant articles and documents

The Silylcupration of Acetylenes: a Synthesis of Vinylsilanes

Bis(dimethylphenylsilyl)copper-lithium (1) reacts with hex-1-yne, propyne, acetylene itself, phenylacetylene, and hex-3-yne to give the products of syn addition of the dimethylphenylsilyl group and the copper.The resultant vinylcopper reagents react with a variety of electrophiles, such as the proton, iodine, acyl and alkyl halides, enones, and epoxides, to give vinylsilanes.With the terminal alkynes, the silyl group becomes attached with a high level of regioselectivity to the terminal carbon atom, with the result that the final products are 2,2-disubstituted vinylsilanes.